Maryam Sedighipoor, Ali Hossein Kianfar, Gholamhossein Mohammadnezhad, Helmar Görls, Winfried Plass

2018/5/1

Inorganica Chimica Acta

476

20-26

Elsevier

Palladium offers various applications in the field of fine chemicals. As one of the most widely
used catalytic metals, due to its high activity and selectivity, there are many possibilities for
carbon-carbon bond formation in the organic synthesis. This study focused on the
condensation reaction between the selected aldehyde or ketone, and 1, 2-
Phenylenediamine; as a result, two different Schiff base ligands were prepared. The reaction
between palladium (II) acetate and Schiff base ligand, in a molar ratio of 1: 1, resulted in the
formation of palladium (II) Schiff base complexes PdL 1 and PdL 2 (L 1= N-2-
hydroxyacetophenon-N′-2, 4-dihydroxbenzaldehyde-1, 2 phenylenediimine, and L 2= N-2-
hydroxyacetophenon-N′-2-hydroxynaphthaldehyde-1, 2 phenylenediimine), as identified
by elemental analysis, FT-IR, UV–Vis and 1 H NMR spectroscopies. The X-ray analysis of …