Homoleptic dinuclear complexes [M 2 (qpyzc) 2 ] (M = Cu ( 1 ) or Ni ( 2 ) were obtained from the readily synthesised trischelate pyrazole‐based qpyzc ligand (H 2 qpyzc = 8‐quinoline‐1 H ‐pyrazole‐3‐carboxamide). Their crystal and molecular structures, magnetic properties, and UV‐vis spectra were reported alongside with DFT and TD‐DFT calculations. Trigonality index τ’ 4 values of 0.25 and 0.21 for the Cu and Ni centres, respectively reveal a marked distortion from square planar geometry. The two metal coordination planes within a complex are tilted towards each other with 40.2(1)° for Cu(II) and 34.5(2)° for Ni(II). The central six‐membered M 2 N 4 metallocycle is almost planar and the two anionic pyrazolate rings are tilted towards each other by 37.4(1)° ( 1 ) and 38.5(2)° ( 2 ), respectively. Regardless of this peculiar bonding situation magnetic measurements on 1 are in line with medium‐sized …